(Press-News.org) How can we engineer materials that are stronger and lighter? What about new materials for extreme conditions such as in jet engines and spacecrafts?
The answer, says Fadi Abdeljawad, an associate professor of materials science and engineering in Lehigh University's P.C. Rossin College of Engineering and Applied Science, might be hidden in the infinitesimally tiny regions, or boundaries, where atoms in crystals come together.
Along with his collaborators at the U.S. Department of Energy's Center for Integrated Nanotechnologies (CINT), Abdeljawad is uncovering how those tiny boundaries have such an enormous impact on the characteristics of nanomaterials.
"Atoms come together to form nanocrystals, which are essentially structures about 1/10,000th the width of a human hair," explains Abdeljawad. "Think of these crystals coming together like pieces of a puzzle, or as tiles on a kitchen floor. Billions of these nanocrystals stack on top of each other to form most engineering materials."
According to the researchers, it is the regions where crystals meet that play an outsized role in determining how a material behaves. Recently, the team’s work was published in Nano Letters, a prestigious journal publishing cutting-edge research in nanoscience and nanotechnology that is known for its high impact.
The article, "Triple Junction Segregation Dominates the Stability of Nanocrystalline Alloys," was published July 29, and explores how tiny features in nanomaterials, known as triple junctions, play a crucial role in maintaining the stability of these materials under high temperatures.
Gold in the corners
Nanocrystalline materials have an extremely fine structure, made up of many tiny crystals. This tiny crystal size can make the material stronger. However, keeping these crystals small and stable over time is challenging because they tend to grow, which can weaken the material.
The researchers in this study discovered that the key to maintaining the stability of these materials at high temperatures lies in triple junctions, corners where three of these nanocrystals meet. Imagine the corners of three puzzle pieces coming together.
What the scientists found is that when certain atoms are added to form an alloy, they prefer to occupy sites at these triple junctions. This "chemical segregation" or gathering of atoms at triple junctions helps to keep the grains from growing, thereby preventing the material from losing its strength over time.
This specific study demonstrated that gold atoms carefully placed at triple junctions in a platinum nanomaterial allowed the material to remain stable in conditions of high temperatures.
"By understanding this process," says Abdeljawad, "scientists can design better nanocrystalline alloys. They can choose specific elements that will go to the triple junctions and stabilize the material. This is particularly important for applications where strength and durability at elevated temperatures are key, such as in the aerospace and energy industries."
Drawing on the power of teamwork
Abdeljawad, a computational materials scientist at Lehigh, performed large-scale computational studies that predicted these results. To validate the models, the computational team partnered with the Center for Integrated Nanotechnologies (CINT). CINT provides advanced tools and expertise for nanoscale research, enabling cutting-edge studies in materials science, nanofabrication, and nanophotonics for scientific and technological advancements.
"This is an outstanding example of collaborative science," says Dr. Brad Boyce, a senior scientist at CINT and a co-author on this study. "Our ideas for how to engineer novel materials by tailoring features at the nanoscale are maturing as a result of the ability to simulate the complex arrangement of atoms that make up these materials."
CINT is one of five Nanoscience User Facilities funded by the US Department of Energy Office of Science. It is jointly operated by Sandia National Labs and Los Alamos National Lab, both based in New Mexico. Two facilities, a Core facility in Albuquerque, and a Gateway facility at Los Alamos, offer unique capabilities and expert scientists to advance nanoscience research. These resources are free to user scientists who are accepted based on a peer-reviewed 2-page proposal.
About Fadi Abdeljawad
Fadi Abdeljawad is an associate professor in the Department of Materials Science and Engineering at Lehigh University.
Prior to joining Lehigh, Abdeljawad served as the Bob and Kaye Stanzione Associate Professor in the Department of Mechanical Engineering at Clemson University, with a joint appointment in the Department of Materials Science and Engineering.
He received his MA and PhD with a primary focus on theoretical and computational materials science from Princeton University. Upon completion of his PhD, he joined the Computational Materials and Data Science Department at Sandia National Laboratories first as a postdoctoral fellow, then as a senior member of the technical staff. Prior to his graduate studies, he worked in the aerospace industry, where he was a materials and stress engineer for Sikorsky Aircraft.
In broad terms, Abdeljawad's research group employs cutting-edge computational tools to advance our understanding of how a materials internal structure (i.e., the microstructure) forms during processing treatments and how such microstructures evolve under the application of external fields, i.e., thermal, mechanical, etc. His group complements these computational efforts with machine learning techniques, which provide a low-computational-cost approach to solving microstructure-based problems. His current research is funded by several agencies including the National Science Foundation, Department of Energy, and Department of Defense.
About The Center for Integrated Nanotechnologies
The Center for Integrated Nanotechnologies (CINT) began operations in 2006 and is jointly administered by Los Alamos National Laboratory and Sandia National Laboratories. This Center makes use of a wide range of specialized facilities including the Microsystems and Engineering Sciences Applications at Sandia and the National High Magnetic Field Laboratory at Los Alamos. CINT's vision is to become a world leading resource for developing the scientific principles that govern the design, performance, and integration of nanostructured materials into the micro and macroscale worlds. This differentiating focus on nanomaterials integration involves the experimental and theoretical exploration of behavior over multiple spatial and temporal length scales, the development of novel synthesis and processing approaches, and an understanding of emergent behavior and new performance regime. CINT is an initiative of the U.S. Department of Energy's Office of Science.
END
Innovating in the corners where atoms meet
Lehigh-Sandia-DOE research captures attention from prestigious Nano Letters journal
2024-10-16
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[Press-News.org] Innovating in the corners where atoms meetLehigh-Sandia-DOE research captures attention from prestigious Nano Letters journal