What if we could revive waste carbon dioxide?

KIMS and KAIST developed catalyst synthesis process and precision control technology to maximize carbon dioxide conversion efficiency

2025-02-21

(Press-News.org) As the severity of climate change and carbon emissions becomes a global concern, technologies to convert carbon dioxide (CO₂) into resources such as chemical fuels and compounds are urgently needed. Dr. Dahee Park’s research team from the Nano Materials Research Division at the Korea Institute of Materials Science (KIMS), has collaborated with Professor Jeong-Young Park’s team from the Department of Chemistry at KAIST to develop a catalyst technology that significantly enhances the efficiency of carbon dioxide (CO2) conversion.

Conventional carbon dioxide (CO2) conversion technologies have faced challenges in commercialization due to their low efficiency relative to high energy consumption. In particular, single-atom catalysts (SACs) suffer from complex synthesis processes and difficulties in maintaining stable bonding with metal oxide supports, which are crucial for stabilizing catalyst particles and enhancing durability. As a result, the performance of these catalysts has been limited.

To overcome these limitations, the research team developed single- and dual-single-atom catalyst (DSAC) technologies and introduced a simplified process to enhance catalyst efficiency. This achievement utilizes electronic interactions between metals in the dual-single-atom catalysts (DSACs), achieving higher conversion rates and excellent selectivity (the ability of a catalyst to direct the production of desired products) compared to existing technologies.

This technology involves a catalyst design approach that precisely controls oxygen vacancies and defect structures within metal oxide supports, significantly enhancing the efficiency and selectivity of carbon dioxide (CO2) conversion reactions. Oxygen vacancies facilitate the adsorption of CO2 on the catalyst surface, while single and dual-single-atom catalysts assist in the adsorption of hydrogen (H2). The combined action of oxygen vacancies, single atoms, and dual-single atoms enables the effective conversion of CO2 with H2 into desired compounds. Notably, dual-single-atom catalysts (DSACs) utilize electronic interactions between two metal atoms to actively regulate the reaction pathway and maximize efficiency.

The research team applied the aerosol-assisted spray pyrolysis method to synthesize catalysts through a simplified process, also demonstrating its potential for mass production. This process involves transforming liquid materials into aerosols (fine mist-like particles) and introducing them into a heated chamber, where the catalyst is formed without the need for complex intermediate steps. This method enables the uniform dispersion of metal atoms within the metal oxide support and precise control of defect structures. By precisely controlling these defect structures, the team was able to stably form single- and dual-single-atom catalysts (DSACs). Leveraging DSACs, they reduced the use of single-atom catalysts by approximately 50% while achieving over twice the CO2 conversion efficiency compared to conventional methods and an exceptionally high selectivity of over 99%.

This technology can be applied across various fields, including chemical fuel synthesis, hydrogen production, and the clean energy industry. Furthermore, the simplicity and high production efficiency of the catalyst synthesis method (aerosol-assisted spray pyrolysis) make it highly promising for commercialization.

Dr. Dahee Park, the lead researcher, stated, “This technology represents a significant achievement in drastically improving the performance of CO2 conversion catalysts while enabling commercialization through a simplified process. It is expected to serve as a core technology for achieving carbon neutrality.” Professor Jeong-Young Park from KAIST added, “This research provides a relatively simple method for synthesizing a new type of single-atom catalyst that can be used in various chemical reactions. It also offers a crucial foundation for the development of CO2 decomposition and utilization catalysts, which is one of the most urgent research areas for addressing global warming caused by greenhouse gases.”

This research was conducted with support from the Korea Institute of Materials Science's core projects, as well as funding from the Ministry of Science and ICT, the Ministry of Trade, Industry and Energy, and the National Research Council of Science and Technology. The findings were published online in Applied Catalysis B: Environmental and Energy (JCR Top 1%, Impact Factor: 20.3), a prestigious journal in the fields of catalysis and energy.

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About Korea Institute of Materials Science(KIMS)

KIMS is a non-profit government-funded research institute under the Ministry of Science and ICT of the Republic of Korea. As the only institute specializing in comprehensive materials technologies in Korea, KIMS has contributed to Korean industry by carrying out a wide range of activities related to materials science including R&D, inspection, testing&evaluation, and technology support.

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