Cu (100) grain boundaries are key to efficient CO electroreduction on commercial copper
Copper (Cu)-based catalysts are currently the most efficient for CO(2)RR to produce high-value C2+ products. Unfortunately, despite recent advances in catalyst design for CO(2)RR, a deep understanding of active sites in Cu-based catalysts remains elusive, primarily due to their poor structural stability under operating conditions, which may lead to significant reconstruction. Consequently, emerging in situ and ex situ characterizations provide ambiguousevidence regarding the true active sites of Cu-based catalysts, including morphology evolution, local pH changes, valence state shifts, ...
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