Phosphorus doping stabilizes high-energy polymeric nitrogen at ambient pressure
Using first-principles calculations, a research group led by Prof. WANG Xianlong from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences, found that phosphorus doping is an effective way to achieve high-energy polymeric nitrogen with black-phosphorus structure (BP-N) stable at ambient pressure.
The research results were published in Matter and Radiation at Extremes.
Cubic gauche nitrogen with diamond-like structure and BP-N with black phosphorus structure, represented by polymeric all-nitrogen materials, are a class of high-energy density materials composed entirely of N-N single bonds, but their samples ...











