Cobalt-induced asymmetric electron distribution boosts photocatalytic hydrogen production efficiency
Hydrogen production from solar-driven water splitting serves as a crucial technology to sustainably access zero-carbon H2 energy. Toward large-scale application, cost-effective cocatalysts—such as transition metal sulfides—with high H2 evolution activity and excellent stability are desperately needed to greatly boost the solar-to-hydrogen conversion efficiency. Unfortunately, the intrinsic symmetrical electron distribution in crystalline metal sulfides usually causes an improper electronic configuration between catalytic S atoms and H intermediates (Had) to form strong S-Had bonds, ...