Researchers first synthesize conjoined bismacrocycle with all phenylene units
The research team led by Prof. DU Pingwu from the University of Science and Technology of China (USTC) of the Chinese Academy of Sciences (CAS) first successfully synthesized an all-phenylene bismacrocycle (bis- means two) with Siamese-twin structure and used fullerene as guest molecules to assemble a peanut-shaped supramolecular complex. This study was published in Angewandte Chemie.
As a new type of carbon material, carbon nanotubes (CNTs) have attracted widespread attention because of their outstanding mechanical and photophysical properties. However, the synthesis of CNTs or CNTs fragments with selective simple structure is still a challenge.
This study reported a conjugated highly strained all-phenylene Siamese-twin bismacrocycle, SCPP[10]. Two phenylene nanorings, [10]CPP, conjoined ...








