Designing for hard and brittle lithium needles may lead to safer batteries
Contrary to previous assumptions, a new study finds that the needle-like lithium dendrites that grow in lithium (Li)-metal batteries are surprisingly strong and brittle, quite unlike soft bulk Li. According to the authors, understanding this brittle fracture behavior provides insights for suppressing dead Li formation and electrolyte cracking, enabling safer and more reliable Li-metal batteries. Li-metal anodes offer the highest specific capacity and the lowest electrochemical potential among all known anode materials, making them highly attractive for use in next-generation battery technologies. However, the use of Li-metal anodes poses significant safety challenges. During ...